Dimethyl carbonate: an environmentally friendly solvent for hydrogen peroxide (H2O2)/methyltrioxorhenium (CH3ReO3, MTO) catalytic oxidations
Author(s)
Date Issued
2007
Type
Article
Abstract
Environmentally friendly oxidations of various organic compounds with the hydrogen peroxide (H2O2)/methyltrioxorhenium(CH3ReO3, MTO) catalytic system have been described in dimethyl carbonate (DMC), a cheap commercially available and benign chemical
having interesting solvating properties, low toxicity and high biodegradability. Oxidations proceeded with good conversions and in good yields. Spectrophotometric analysis demonstrated that the [CH3ReO(O–O)2] complex was formed in DMC and that it was stable for several days at room temperature.
Additional information
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Citation
Bernini, R. et al. 2007. Dimethyl carbonate: an environmentally friendly solvent
for hydrogen peroxide (H2O2)/methyltrioxorhenium
(CH3ReO3, MTO) catalytic oxidations. "Tetrahedron" 63: 6895-6900
for hydrogen peroxide (H2O2)/methyltrioxorhenium
(CH3ReO3, MTO) catalytic oxidations. "Tetrahedron" 63: 6895-6900
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