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  5. A methodological approach to study the stability of selected watercolours for painting reintegration, through reflectance spectrophotometry, Fourier transform infrared spectroscopy and hyperspectral imaging

A methodological approach to study the stability of selected watercolours for painting reintegration, through reflectance spectrophotometry, Fourier transform infrared spectroscopy and hyperspectral imaging

Author(s)
Pelosi, Claudia  
Capobianco, Giuseppe
Agresti, Giorgia
Bonifazi, Giuseppe
Morresi, Fabio
more
Date Issued
2018
Type
article
Volume
198
Start Page
92
End Page
106
DOI
10.1016/j.saa.2018.03.008
Journal
SPECTROCHIMICA ACTA. PART A, MOLECULAR AND BIOMOLECULAR SPECTROSCOPY  
Abstract
The aim of this work is to investigate the stability to simulated solar radiation of some paintings samples through a new methodological approach adopting non-invasive spectroscopic techniques. In particular, commercial watercolours and iron oxide based pigments were used, these last ones being prepared for the experimental by gum Arabic in order to propose a possible substitute for traditional reintegration materials. Reflectance spectrophotometry in the visible range and Hyperspectral Imaging in the short wave infrared were chosen as non-invasive techniques for evaluation the stability to irradiation of the chosen pigments. These were studied before and after artificial ageing procedure performed in Solar Box chamber under controlled conditions. Data were treated and elaborated in order to evaluate the sensitivity of the chosen techniques in identifying the variations on paint layers, induced by photo-degradation, before they could be observed by eye. Furthermore a supervised classification method for monitoring the painted surface changes adopting a multivariate approach was successfully applied.
Subjects

Watercolours stabilit...

Fourier transform inf...

Reflectance spectropho...

Hyperspectral imaging...

Multivariate analysis...

Handle
http://hdl.handle.net/2067/47571
File(s)
Thumbnail Image
Name

PELOSI ET AL_FINAL_ACCEPTED_SAA.pdf

Size

1.31 MB

Format

Adobe PDF

Checksum (MD5)

2380e8ff03d1750fb99cb0207fba223a

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