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Please use this identifier to cite or link to this item: http://hdl.handle.net/2067/1881

Title: Chemoselective and efficient carboxymethylation of the alcoholic chain of phenols by dimethyl carbonate (DMC).
Authors: Bernini, Roberta
Mincione, Enrico
Crisante, Fernanda
Barontini, Maurizio
Fabrizi, Giancarlo
Gentili, Patrizia
Keywords: Chemoselective carbomethoxylation
Dimethyl carbonate
Carboxymethylated hydroxytyrosol
Issue Date: 2007
Publisher: Elsevier Ltd
Citation: Bernini, R. et al. 2007. Chemoselective and efficient carboxymethylation of the alcoholic chain of phenols by dimethyl carbonate (DMC). "Tetrahedron Letters" 48(39): 7000-7003.
Abstract: The efficiency of dimethyl carbonate (DMC) as chemoselective carbomethoxylating agent of the alcoholic chain of phenols has been investigated. In the presence of 1,8-diazabicyclo[5.4.0]undec-7-ene (DBU) or sulfuric acid as catalysts. New carbomethoxylated phenolic compounds were obtained in quantitative yields. A new efficient derivatization of the aliphatic alcoholic chain of the precious natural hydroxytyrosol is described, which increases the lipophilicity of the hydroxytyrosol. The antioxida
Description: L'articolo è disponibile sul sito dell'editore: http://www.sciencedirect.com
URI: http://hdl.handle.net/2067/1881
ISSN: 0040-4039
Appears in Collections:DABAC - Archivio della produzione scientifica

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