The DSpace digital repository system captures, stores, indexes, preserves, and distributes digital research material. http://http://dspace.unitus.it:80 2013-05-25T06:47:24Z 2013-05-25T06:47:24Z Bernini, Roberta Mincione, Enrico Barontini, Maurizio Crisante, Fernanda Fabrizi, Giancarlo Gambacorta, Augusto http://hdl.handle.net/2067/1879 2011-06-29T14:21:07Z 2006-12-31T23:00:00Z

Title: Dimethyl carbonate: an environmentally friendly solvent for hydrogen peroxide (H2O2)/methyltrioxorhenium (CH3ReO3, MTO) catalytic oxidations Authors: Bernini, Roberta; Mincione, Enrico; Barontini, Maurizio; Crisante, Fernanda; Fabrizi, Giancarlo; Gambacorta, Augusto Abstract: Environmentally friendly oxidations of various organic compounds with the hydrogen peroxide (H2O2)/methyltrioxorhenium(CH3ReO3, MTO) catalytic system have been described in dimethyl carbonate (DMC), a cheap commercially available and benign chemical having interesting solvating properties, low toxicity and high biodegradability. Oxidations proceeded with good conversions and in good yields. Spectrophotometric analysis demonstrated that the [CH3ReO(O–O)2] complex was formed in DMC and that it was stable for several days at room temperature. Description: L'articolo è disponibile sul sito dell'editore: http://www.sciencedirect.com

2006-12-31T23:00:00Z